Abstract
Abstract Cis-1,2,3,4,4a,5,6,8a-octahydro-2-methyl-4a-phenylisoquinolin-3-one was obtained by cyclization of the acyliminium ion intermediate, derived from the corresponding amide. Reduction of this cyclization product with LiAlH4 in THF afforded cis-1,2,3,4,4a,5,6,8a-octahydro-2-methyl-4a-phenylisoquinoline. In a similar way, the octahydro-4a-(2-methoxyphenyl) isoquinolin-3-one was also prepared from the corresponding amide.
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