Abstract
AbstractA new 3D MnII metal‐organic framework compound {Mn(phen)(dcbp)}n (H2dcbp = 4,4‐dicarboxy‐2,2′‐bipyridine, phen = 1,10‐phenanthroline) was isolated under hydrothermal conditions and structurally characterized. In the compound, the dcbp ligand is deprotonated to give a neutral species (metal:ligand with 1:1 stoichiometry). Along the c axis, the neighboring MnII ions are linked by two carboxylate bridges in µ2‐coordinating mode to generate a 1D zigzag chain, and these chains are interlinked by dicarboxylate groups of long dcbp ligands to generate a 3D (4,4)‐connected structure with the (42.84) net topology. IR and UV/Vis spectroscopy and variable temperature magnetic susceptibility measurements were made, which indicated weak antiferromagnetic interactions between the MnII ions of the compound.
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