Abstract

Abstract A new three-dimensional (3D) framework, [Cu4(btp)4Cu(H2O)2(PW11CuO39)]·2H2O (1) (btp = 1,3-bis(1,2,4-triazol-1-y1)propane), was synthesized under hydrothermal conditions. The 3D framework of compound 1 is constructed by two kinds of chains: inorganic Keggin chain sharing terminal O atoms and tetra-nuclear metallamacrocyclic chain.

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