A Nanoporous Polymer Modified with Hexafluoroisopropanol to Detect Dimethyl Methylphosphonate.

Abstract

The increasing threat of nerve agents has prompted the need for gas sensors with fast response, high sensitivity, and good stability. In this work, the hexafluoroisopropanol functional group was modified on a porous aromatic framework material, which served as a sensitive material for detecting dimethyl methylphosphonate. A nerve agent sensor was made by coating sensitive materials on a surface acoustic wave device. Lots of pores in sensitive materials effectively increase the specific surface area and provide channels for diffusion of gas molecules. The introduction of hexafluoroisopropanols enables the sensor to specifically adsorb dimethyl methylphosphonate and improves the selectivity of the sensor. As a result, the developed gas sensor was able to detect dimethyl methylphosphonate at 0.8 ppm with response/recovery times of 29.8/43.8 s, and the detection limit of the gas sensor is about 0.11 ppm. The effects of temperature and humidity on the sensor were studied. The results show that the baseline of the sensor has a linear relationship with temperature and humidity, and the temperature and humidity have a significant effect on the response of the sensor. Furthermore, a device for real-time detection of nerve agent is reported. This work provides a new strategy for developing a gas sensor for detecting nerve agents.