Abstract

To date it has not been possible to produce metallic glass strips with a thickness larger than 150 μm via single-roller melt spinning technique, and it remains challenging to produce thick metallic glass strips. In this work, a multiple twin-roller casting technique is proposed for producing thick metallic glass and metallic glass composite strips. A triple twin-roller casting device, as a specific case of the multiple twin-roller, was designed and manufactured. The triple twin-roller device possesses a high cooling rate and involves a long contact time between the melt and the strip, which makes it an efficient technique for producing metallic glass strips that avoids crystallization, although the solidification temperature ranges of metallic glasses are as wide as several hundred Kelvins. The two prepared metallic glass (MG) strips are in a fully amorphous state, and the MG strip shows excellent capacity of stored elastic energy under 3-point bending. Furthermore, the Ti-based metallic glass composite strip produced via the triple twin-roller casting exhibits a novel microstructure with much finer and more homogenously orientated β-Ti crystals, as compared with the microstructure of metallic glass composites produced by the common copper mold casting technique.

Highlights

  • Metallic glasses (MGs) and metallic glass composites (MGCs) containing in-situ formed crystalline phases are potential structural materials due to their excellent mechanical properties, including high strength, high hardness and high elastic limit [1,2,3,4,5]

  • MG strip with a thickness larger than 150 μm cannot be produced via single-roller melt spinning technique [14,15,16], and an efficient technique is required for making MG and MGC thick strips

  • The results show that triple twin-roller casting proposed multiple twin-roller casting technique

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Summary

Introduction

Metallic glasses (MGs) and metallic glass composites (MGCs) containing in-situ formed crystalline phases are potential structural materials due to their excellent mechanical properties, including high strength, high hardness and high elastic limit [1,2,3,4,5]. The in-situ formed crystals in MGCs are elaborately introduced for improving the plasticity of MGs [6,7,8,9,10,11]. MG and MGC strips, as initial materials, are widely used for making products via the thermoplastic forming process in the super-cooled liquid region [12,13]. MG and MGC strips are ideal elastic materials for springs and clock winders [1,12]. MG strip with a thickness larger than 150 μm cannot be produced via single-roller melt spinning technique [14,15,16], and an efficient technique is required for making MG and MGC thick strips

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