Abstract
The interaction between monomeric and dimeric aqueous oleate species and ionizing groups at the goethite—water interface has been constructed to analyze experimental surface change titration and oleate adsorption isotherms. The binding constants that emerge and the pH—concentration distribution of surface oleate complexes support the concept of anion-neutral molecule coadsorption or acid soap dimer adsorption in the region where precipitation of oleic acid and/or ferric oleate is precluded.
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