Abstract
The Cu/SSZ-13 catalyst can provide multiple active sites for the ammonia selective catalytic oxidation (NH3-SCO), the influence of which can be tuned by varying the Si/Al ratio. The latter parameter was found to influence the surface acidic property and the Cu species distribution, which are critical for NH3 adsorption and activation. It was found that both CuO and isolated Cu2+ ions coexist in Cu/SSZ-13 catalyst. The selected Si/Al-20 sample with the highest content of CuO species and abundant acidity exhibited the best NH3-SCO performance.
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