Abstract

HighlightsThe introduction of PEG 400 additive in the aqueous electrolyte enables regulating the Zn2+ solvation structure and inhibiting the ionization of free water molecules.Such anti-proton electrolyte can not only reduce the lattice expansion of cathode hosts and inhibit the associated by-products, but also guide the uniform Zn deposition and inhibit the hydrogen evolution reaction.A high-rate Zn-V2O3/C battery with 18,000-cycle shelf-life can be demonstrated via the integrated synergetic modification mechanism.

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