A Multichannel Screen-Printed Carbon Electrode Based on Fluorinated Poly(3-octylthiophene-2,5-diyl) and Purified Mesoporous Carbon Black Simultaneously Detects Na+, K+, Ca2+, and NO2.

Abstract

Preparation of nanocomposites based on fluorinated poly(3-octylthiophene-2,5-diyl) (POTF) and purified mesoporous carbon black (PMCB) as the solid-contact layer of a screen-printed carbon electrode (SPCE) is proposed. POTF is used as a dispersant for PMCB. The obtained nanocomposites possess unique characteristics including high conductivity, capacitance, and stability. The SPCE based on POTF and PMCB is characterized by electrochemical impedance spectroscopy and chronopotentiometry, demonstrating simultaneous detection of Na+, K+, Ca2+, and NO2- ions with detection limits of 10-6.5, 10-6.4, 10-6.7, and 10-6.3 M, respectively. Water layer and anti-interference tests revealed that the electrode has high hydrophobicity, and the static contact angle is >140°. The electrode shows excellent selectivity, repeatability, reproducibility, and stability and is not easily affected by light, O2, or CO2.