Abstract

Cast CF3M duplex stainless steel having 25% of ferrite in volume fraction was aged at 723 K for time periods up to 10000 h. Phase decomposition of ferrite was investigated by Mossbauer spectroscopy. Ferrite decomposed initially via a spinodal process to finally yield the Fe-rich and the Cr-rich phase. The hyperfine magnetic field distribution obtained from the experimental Mossbauer spectrum was analyzed by assuming trinomial distribution of main constituent atoms Fe, Cr, Ni to determine Cr and Ni content of the Fe-rich phase. Main compositions of the phase were 84 at.% Fe, 11 at.% Cr, 5 at.% Ni.

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