Abstract
Over the past few years, major progress in Polymerization-induced self-assembly(PISA) has had a substantial effect on the preparation of inverse bicontinuous phases particles. However, despite recent advances, almost no detailed studies are reported on cosolvent. We report here a strategy to form the inverse phases particles using cosolvents in PISA. Effect of core-forming block length, the solvent composition, and solid content on particle morphology were investigated. This convenient synthetic route to porous polymer has the potential to be useful in related fields where both templates and nanoreactors.
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