Abstract
The catalytic formation of ammonia synthesis through dimers N 2 and H 2 has already been studied through Monte-Carlo simulation via a model based on a Langmuir–Hinshelwood (thermal) mechanism. The results of this study are well known. Here, we have studied this reaction on the basis of a non-thermal model, which involves the precursor motion of a H 2 molecule. The most interesting feature of this model is that it yields a steady reactive window, which is separated by continuous and discontinuous irreversible phase transitions.
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