Abstract
It is shown theoretically that the experimentally observed shifts of isoelectric points of various oxide surfaces toward more basic pH's in concentrated and mixed-solvent electrolyte solutions can be explained by a model previously used to predict the phenomenon of “coagulation zones” in the stability of colloids with adsorption layers of nonionic polymers. The model assumes the standard solvation energies of ions near a solid–liquid interface to be different from those in the bulk due to changes in the solvent structure. To reproduce the trends of experimental data in aqueous solutions, the solubilities of both cations and anions must be decreased, but for cations that must occur to a smaller extent. In mixed solvents a qualitative agreement with the experimental data is achieved by assuming that there is a water-enriched layer near the oxide surface.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.