Abstract
The non-isothermal, two-phase membrane electrodes assembly numerical model previously developed in Part I [J. Electrochem. Soc., 164, 6, F530 (2017)] is validated by comparing to experimentally measured electrochemical performance data under various operating conditions. Water accumulation in catalyst layer (CL) and gas diffusion layer (GDL) are also compared to the neutron and X-ray imaging data and shown to be in agreement. Water fluxes at cathode and anode boundaries and phase change induced flow are analyzed and compared to experimental data. Simulation results indicate that when liquid water is present, reactant transport in the catalyst layer is the key factor limiting fuel cell performance. The model shows that at high relative humidity, 80°C is the optimal operating temperature in order to delay water accumulation without degrading performance due to oxygen dilution by water vapor. The impact of CL and GDL hydrophilic volume fraction, hydrophobic contact angle and pore size distribution on performance are also studied. Results suggest that when liquid water is present, GDL parameters have minimal effect on performance and a CL should have a large hydrophobic contact angle, a low hydrophilic volume fraction, and large pore radius.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
