Abstract

A theoretical approach, in which the rotational degrees of freedom are treated quantum mechanically while translational degrees of freedom classically or semiclassically, is applied to calculate the total and final-state specific cross sections for the reaction H- + H → H2( v, j) + e- in the range of low collision energies ( E = 1-754 meV). The calculated cross sections agree well with the existing experimental and theoretical results. Results are also presented for the inverse dissociative attachment process: H2( v, j) + e- → H- + H.

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