Abstract
The crystal structures of bis-3,5-dimethylpyrazole copper(II) 4-methylbenzoate, bis-3,5-dimethylpyrazole copper(II) 3-methylbenzoate, bis-3,5-dimethylpyrazole copper(II) 4-nitrobenzoate show that 3,5-dimethylpyrazole in the cis or trans positions is related to axial distortion of Cu-O bond in carboxylate groups. A metastable mixed carboxylate co-ordination polymer presumably intermediate to the one described above which has alternate paddlewheel and mononuclear units is structurally characterized.
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