A Mild Phosphine-Free Synthesis of Alkylamine-Capped CdSe Nanocrystals

Abstract

A new phosphine-free approach has been developed to synthesize high-quality cadmium selenide (CdSe) nanocrystals with cubic zinc-blende structure, by using the highly reactive selenium (Se) precursor at milder temperature than that used in the traditional phosphine route. This Se precursor was obtained from the reduction of Se powder by sodium borohydride in N,N-dimetbylformamide, in the absence of phosphine. Without the addition of other long-chain coordinating substances in this approach, the alkylamines such as dodecylamine (DDA) and octylamine (OA) were used as reaction solvents, and they also acted as surface capping reagents to produce DDA-capped and OA-capped CdSe NCs, respectively. The rapid nucleation and slow growth were observed by ultraviolet-visible absorption spectrum. The resulting OA-capped CdSe NCs grew faster compared with DDA-capped CdSe NCs under the same other conditions. These as-synthesized CdSe nanocrystals showed relatively narrow size distribution and high photoluminescence quantum efficiency (up to 9.4% for OA-capped CdSe NCs). This mild approach is low cost, relatively low danger and high production yield (approximately 80%), indicating that it is very effective for the phosphine-free synthesis of alkylamine-capped CdSe nanocrystals.