Abstract

Analytical electron microscopy, AEM, has provided valuable information on the structure, composition, location and size of metal clusters and/or crystallites supported on amorphous or crystalline metal oxide materials. Although this information is vital to the understanding of how a catalyst functions, the catalytic reaction is usually more complex. Many variables must be taken into account to evaluate properly a catalyst. Improper selection of process variables can make a good catalyst perform poorly. Consequently, focusing on specific metal site properties may not always be the appropriate direction to take when evaluating a supported metals catalyst problem.To help the microscopist appreciate the complexity of the problem, the following examples were chosen to illustrate this point. Reforming catalysis involves a complex set of reactions to convert naphtha feed to high octane gasoline. The catalyst is comprised of highly dispersed Pt on a high surface area alumina with Cl. The catalyst is dual functional requiring both metal site activity for dehydrogenation and acidity for isomerization and cyclization.

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