A Michael-type reaction between acrylato ions and ethylenediamine coordinated to Ni(II). Synthesis, crystal structure and magnetic properties of [Ni2(EDDP)2(H2O)2] · 2H2O (H2EDDP = ethylenediamine-N,N-dipropionic acid)

Abstract

Abstract The reaction between NiCO3 · Ni(OH)2, acrylic acid and ethylenediamine in a 2:4:1 molar ratio affords the binuclear complex, [Ni2(EDDP)2(H2O)2] · 2H2O 1. The organic ligand, EDDP2− (the dianion of the ethylenediamine-N,N-dipropionic acid ligand), results from the addition of one amine group to the carbon–carbon double bonds of two acrylato ions. The crystal structure of 1 consists of neutral centrosymmetric entities, with the nickel ions connected by two carboxylato groups, each one acting as a monoatomic bridge. The intramolecular Ni⋯Ni distance is 3.212 A. The metal ions exhibit an octahedral geometry. The cryomagnetic investigation of 1 reveals an antiferromagnetic coupling of the nickel(II) ions (J = −21.8 cm−1, H = −JSNi1SNi2).