Abstract

A method to investigate the characteristics of a geling system is presented. It is known that gelation time is prolonged from the value predicted by the Flory-Stockmayer model because of intraparticle cross-linking. Another effect should be taken into consideration. If hard particles are formed in the course of the reactions, the functional groups buried in the inner part of the particles may find it difficult to participate in the interparticle cross-linking. This effect is studied using the coagulation kinetics

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