Abstract

In order to realize the resource utilization of bloom algae from Lake Chao, this study presents the use of fresh algae to improve the mechanical and biological properties of low-density polyethylene (LDPE). In this study, the algae and LDPE were used as raw materials, maleic anhydride grafted polyethylene (PE-g-MAH), polyethylene wax (PE-wax) and white oil, and glycerin were used as the compatibilizer, lubricant, and plasticizer, respectively. The single factor experiments were conducted with these three individual factors, and the response surface methodology technique was used to optimize the process conditions. In the single factor experiments, the mechanical properties of the composites increased with additions of PE-g-MAH, PE-wax/white oil, and glycerin. Both flexural strength and flexural modulus were maximized to optimize the preparation conditions. The optimum preparation conditions were found as follows: algae powder of 15.00 wt%, LDPE of 85.00 wt%, PE-g-MAH of 4.00 wt%, lubricant of 2.67 wt%, and glycerin of 3.00 wt%. This resulted in 11.60 MPa of tensile strength, 9.95 MPa of flexural strength, and 241.00 MPa of flexural modulus. The mechanical properties of composites were greatly improved compared with the absence of additives. In addition, compared with LDPE resin, the degradability of the composite was improved, and the weight loss rate was 7.73% after 6 months. The results recommended that the composites of the algae from Lake Chao and LDPE resin could be a useful material in the packaging field. Generally, the prepared composite particles can be used to produce foam products, packaging bags, or hard packing boxes with special shapes. It is more environmentally friendly, and more able to meet the challenges of sustainable development.

Highlights

  • In recent years, algal bloom phenomena have occurred frequently in Lake Chao, which is one of the five largest freshwater lakes in China

  • The use of algal bloom algae powder as a raw material to prepare composites combined with low-density polyethylene (LDPE) is equivalent to replacing the use of part of the LDPE resin, which indirectly reduces the use of plastic products to improve their degradation properties

  • The LDPE was purchased from Dongguan Jiuma Plastic Industry Co., Ltd (China), maleic anhydride grafted polyethylene (PE-g-MAH) was purchased from Hefei Youshuo Scientific Instrument Co., Ltd (China), polyethylene wax (PE-wax) was purchased from Anhui Jiuyi Chemical Co., Ltd. (China), white oil was purchased from Guangzhou Teyun Trading Co., Ltd. (China), and glycerin was purchased from Wuxi Yatai United Chemical Co., Ltd. (China)

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Summary

Introduction

Algal bloom phenomena have occurred frequently in Lake Chao, which is one of the five largest freshwater lakes in China. The mode of production is of great significance for the resource utilization of algae from algal bloom, and its production cost is lower and it is more adaptable to market demand. The combination of the Lake Chao algae powder with the LDPE material can provide a more extensive and direct treatment for algae harvested through mechanical fishing. The flexural properties of the LDPE can be improved by the addition of Lake Chao algae powder. The use of algal bloom algae powder as a raw material to prepare composites combined with LDPE is equivalent to replacing the use of part of the LDPE resin, which indirectly reduces the use of plastic products to improve their degradation properties. Research on the preparation of bio-plastics from algae powder is rare, so this work is expected to provide some concepts and references to develop and research new biodegradable materials in the future

Materials
Preparation of Algae Powder
Single Factor Experiments
Design Experiment Based on Response Surface Method
Weight Loss Rate Experiment
Measurements and Characterization
Analysis of Single Factor Experimental Results
Behavioral Characterization of the Combined Algae Powder and LDPE Resin
Methodology
Response Surface Methodology Advantage
Experimental Design and Results
Response Surface Analysis
Conclusions
Full Text
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