Abstract
A new method for determining the stability constants of mixed complexes is proposed which is especially appropriate when only the mixed complex 1:1:1 is formed. In order to verify this method, the coordinate system Pb(II)-SCN −-NO − 3 has been studied polarographically in aqueous medium of a constant ionic strength of μ = 1.0 M. Using our knowledge of the stability constants of simple complexes and applying this method we obtain β 11 = 8 for the mixed complex.
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