Abstract
AbstractA method for the construction of the essentially idempotent and Hermitian diagonal elements of the matric algebra of the permutation group Sn is proposed. For the irreducible representation [λ] = [λ1, λ2] characterising a spin state S of an n‐electron system, it is found that this method generates the complete set of spin projections from the appropriate primitive spin functions. The method is applied to a 7‐electron system in the spin state S = MS = 1/2 and the results are listed in the Appendix.
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