Abstract
The spin-lattice relaxation time (T1) plays a crucial role in the study of spin dynamics, signal optimization and data quantification. However, the measurement of chemical shift-specific T1 constants is hampered by the magnetic field inhomogeneity due to poorly shimmed external magnetic fields or intrinsic magnetic susceptibility heterogeneity in samples. In this study, we present a new protocol to determine chemical shift-specific T1 constants in inhomogeneous fields. Based on intermolecular double-quantum coherences, the new method can resolve overlapped peaks in inhomogeneous fields. The measurement results are in consistent with the measurements in homogeneous fields using the conventional method. Since spatial encoding technique is involved, the experimental time for the new method is very close to that for the conventional method. With the aid of T1 knowledge, some concealed information can be exploited by T1 weighting experiments.
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