Abstract
This paper discusses methods of assessing oil and gas resources and evaluating their mobility in shale reservoirs using programed pyrolysis data in conjunction with reservoir engineering parameters derived from production data. The hydrocarbon resource is calculated from the measured free hydrocarbon by programed pyrolysis with correction of evaporative loss that occurred during coring, storage and sample preparation. The correction takes account of the loss of light hydrocarbon fluids as a result of phase change during core retrieval to the surface and evaporative loss related to storage and sample preparation. Based on their response to ramping temperature during sample pyrolysis and thermal equilibrium behavior of distinct petroleum products at different thermal maturities, the estimated oil and gas resources are divided into three categories: non-movable, restricted, and movable to characterize the mobility of the petroleum fluids. The mobility classification is compared with oil compositional grouping based on evaporative kinetics of petroleum products in rock samples to examine their affinity. Pyrolysis analysis results from naturally matured samples and production data from different fluid zones in the Duvernay Shale resource play in Western Canada Sedimentary Basin (WCSB) were used to demonstrate the application of the proposed method. While the mobility of petroleum fluids increases with thermal maturation in general, the total movable resource reaches its maximum at the end of oil generation window, then declines as a result of massive loss due to hydrocarbon expulsion towards to gas window where liquids are thermally cracked to gaseous hydrocarbons. Compositional grouping based on evaporative kinetics does not show a complete accordance with mobility grouping, suggesting composition is only one of many factors affecting hydrocarbon fluid flow in shale reservoir. More studies are required to better understand the fundamentals of oil mobility in shale reservoir.
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