Abstract
A new member of fluorooxoborates, Li2Na0.9K0.1B5O8F2, was obtained in the sealed system, and single-crystal X-ray diffraction was used to determine its structure. It contains a three-dimensional framework stacking of [B5O8F2]3- layers extending into the ac plane. Detailed structural comparisons among all of the fluorine-containing alkali-metal borates suggest that the [B5O8F2]3- layer composed of the new fundamental building blocks B5O10F2 represents a new structure type of fluorooxoborate. The IR spectrum verifies its structural validity. The deep-ultraviolet spectral measurement shows that it has no obvious absorption in the range of 180-300 nm, and its cutoff edge is under 180 nm. In addition, theoretical calculations were done to help us understand its electronic structure and optical properties.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
