A Mechanochromic and Photochromic Dual-Responsive Co-assembly with Multicolored Switch: A Peptide-Based Dendron Strategy.

Abstract

In this contribution, we report a unique co-assembly composed of pyrene and spiropyran that were linked separately at the focal point of the same peptide-based dendron (Phe-Glu), in which the dendrons offer driving forces for the coaggregation. A series of co-assemblies with different weight ratios (Py-Phe-Glu/SP-Phe-Glu) were prepared and the morphology could be tuned. It is found that the resulting stable co-assembled organogel is double switchable triggered by light and heat. TEM revealed that, in the xerogel, Py-Phe-Glu formed rigid rod nanofibers with large diameters and acted as a rigid sketelon where the gracile interwoven fibrous structure of SP-Phe-Glu grew. More interestingly, the original powder of the co-assembled xerogel (1.0 mg/0.1 mg) not only displayed a sequential high-contrast tricolored switch from dark blue to bright cyan and to red under external force but also presented multistate accessible photochromic properties. Such mechanochromic and photochromic behaviors of the xerogel are mainly due to the transition of different excimers of pyrene and the force/photoinduced ring-opening reaction of spiropyran. It is rarely reported that self-assembled soft materials achieve mechanochromic and photochromic dual-responsive behaviors with a high-contrast multicolored switch. We believe the co-assembly strategy based on polypeptide dendrons can be extended to other systems for establishing novel intelligent fluorescent materials.