Abstract
In this contribution, we report a unique co-assembly composed of pyrene and spiropyran that were linked separately at the focal point of the same peptide-based dendron (Phe-Glu), in which the dendrons offer driving forces for the coaggregation. A series of co-assemblies with different weight ratios (Py-Phe-Glu/SP-Phe-Glu) were prepared and the morphology could be tuned. It is found that the resulting stable co-assembled organogel is double switchable triggered by light and heat. TEM revealed that, in the xerogel, Py-Phe-Glu formed rigid rod nanofibers with large diameters and acted as a rigid sketelon where the gracile interwoven fibrous structure of SP-Phe-Glu grew. More interestingly, the original powder of the co-assembled xerogel (1.0 mg/0.1 mg) not only displayed a sequential high-contrast tricolored switch from dark blue to bright cyan and to red under external force but also presented multistate accessible photochromic properties. Such mechanochromic and photochromic behaviors of the xerogel are mainly due to the transition of different excimers of pyrene and the force/photoinduced ring-opening reaction of spiropyran. It is rarely reported that self-assembled soft materials achieve mechanochromic and photochromic dual-responsive behaviors with a high-contrast multicolored switch. We believe the co-assembly strategy based on polypeptide dendrons can be extended to other systems for establishing novel intelligent fluorescent materials.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.