Abstract
A wide variety of polyether-based networks were prepared and tested in terms of ionic conductivity as a function of the type and concentration of the salt added, the structure of the reticulate and the temperature. This study includes ionomeric networks. The results indicate the occurrence of polyether chain partitioning by the dissociated salt and formation of quadrupoles binding two such chains. A model is proposed to rationalize the conduction mechanism on the basis of the overall experimental evidence.
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