Abstract
The photo-oxidation of toluene/NO x exhibits several features that distinguish it from olefin and paraffin smog systems: highly photolytic products, a relatively low production rate of peroxy radicals, and strong sinks for NO x. The underlying chemical behavior of the toluene smog system is discussed and a kinetic simulation mechanism is presented. The mechanism simulates toluene smog chamber experiments conducted at two facilities: the University of California at Riverside evacuable chamber, and the outdoor smog chamber at the University of North Carolina.
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