Abstract

This paper describes a manometric method for the determination of chemical diffusion coefficients from gas/solid equilibration kinetics for electrode materials of the type (La,Sr)(Mn,Fe,Co)O 3. The equilibration kinetics was monitored by measurements of the p(O 2) changes during a reaction between oxygen and the electrode material involving both oxidation and reduction experiments in the temperature range 773–1123 K. Activation energy of the chemical diffusion measurements at different temperatures was determined during both oxidation and reduction experiments. The chemical diffusion coefficients measured by the present manometric method on La 0.8Sr 0.2MnO 3−δ have been compared with those reported in the literature.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.