Abstract
Der Kohlenstoff-Phosphor-Antimon-Käfig von P2C2tBu2SbCl (siehe Bild) liegt in einer Schmetterlingsstruktur vor, während das Phosphoranalogon P2C2tBu2PCl die tricyclische Struktur bevorzugt. DFT-Rechnungen zeigen, dass schon kleine Änderungen der elektronischen Struktur wegen des inerten Ionenpaars zu deutlichen Unterschieden in Struktur und Dynamik führen.
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