Abstract
Fluxional platinum and “naked” alkynyl rods: The first example of a Pt3C2 complex with a “naked” C≡C2− unit linked to three unsupported platinum(II) fragments has been reported and characterized by X-ray crystallography. An interesting fluxional motion, which involves σ–π alkynyl exchange, has been revealed in solution (see figure). The photophysical properties have been studied and correlate with theoretical calculations.
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