Abstract

A new 1D Zn-based coordination polymer (CP), {[Zn(HBTB)(pdp)]·H2O} (1) (H3BTB=1,3,5-benzenetribenzoic acid and pdp=2-(4,6-di(pyridine-2-yl)pyridine- 2-yl)pyridine), has been synthesized under solvothermal condition and structurally characterized. The compound displays intense luminescence in solid state at room temperature with high thermal stability. Interestingly, Luminescent studies indicate that 1 could be an efficient multifunctional fluorescence material for high sensitivity metal ions, anions and organic small molecules, especially for Cu2+, CrO42− and nitrobenzene (NB) by luminescent quenching. The probable quenching mechanism of different analytes was also discussed.

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