A low temperature synthesis of activated carbon from the bio waste for simultaneous electrochemical determination of hydroquinone and catechol

Abstract

In the present study, the simultaneous determination of hydroquinone (HQ) and catechol (CC) was investigated by using the activated carbon (AC) from dead mango leaves at a low temperature (600°C). The synthesized AC exhibited a high surface-area of ∼782m2g−1. The AC modified electrode exhibited a sensitive and selective detection of HQ and CC than that of other AC modified electrodes which prepared at quite higher temperatures (700°C, 800°C, 900°C). The AC600 holds its high selectivity towards the potentially interfering species compared with other AC modified electrodes. The fabricated AC modified electrode showed a well defined redox peak for HQ and CC with a better peak separation compared with unmodified electrode. The AC modified electrode showed enhanced peak current response with a lower potential of HQ (0.11V) and CC (0.22V) compared with bare electrode. The linear response range of HQ and CC was found from 10 to 100 and 5 to 100nM with the sensitivity of 5.19 and 6.59μAμM−1cm−2, respectively. The limit of detection (LOD) was found as 3nM for HQ and 2nM for CC at the AC modified electrode, which is the lowest LOD for HQ and CC that ever been reported using carbon nanomaterials modified electrodes.