Abstract

The kinetic energy dependence of the charge reactions 3He + + 4He ⇌ 3He + 4He + was investigated using a modified ion cyclotron double resonance technique. The rate constant increases monotonically from (5.0 ± 0.5) × 10 −10 cm 3 molecule −1 sec −1 at 0.1 eV to 55 × 10 −10 cm 3 molecule −1 sec −1 at a relative kinetic energy of 25 eV. The results compare favorably with theoretical predications for symmetric resonance charge transfer.

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