Abstract

Attention to Black Carbon (BC) has been rising due to its effects on human health as well its contribution to climate change. Measurements of BC are challenging, as currently used devices are either expensive or impractical for continuous monitoring. Here, we propose an optoacoustic sensor to address this problem. The sensor utilizes a novel ellipsoidal design for refocusing the optoacoustic signal with minimal acoustic energy losses. To reduce the cost of the system, without sacrificing accuracy, an overdriven laser diode and a Quartz Tuning Fork are used as the light source and the sound detector, respectively. The prototype was able to detect BC particles and to accurately monitor changes in concentration in real time and with very good agreement with a reference instrument. The response of the sensor was linearly dependent on the BC particles concentration with a normalized noise equivalent absorption coefficient (NNEA) for soot equal to 7.39 × 10−9 W cm−1 Hz−1/2. Finally, the prototype was able to perform NO2 measurements, demonstrating its ability to accurately monitor both particulate and gaseous pollutants. The proposed sensor has the potential to offer a significant economic impact for BC environmental measurements and source appointment technologies.

Highlights

  • Black Carbon (BC) is an important component of atmospheric particulate matter that has been recently attracting increased attention by the scientific community due to its effects on human health and the climate [1,2]

  • Light absorption is expected to arise from both BC particles and NO2

  • In a third experiment (Figure 4c), an Activated Carbon (AC) filter was used to filter out the gaseous components, including NO2

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Summary

Introduction

Black Carbon (BC) is an important component of atmospheric particulate matter that has been recently attracting increased attention by the scientific community due to its effects on human health and the climate [1,2]. BC mostly comprises combustion-generated particles in the range of 20–200 nm formed by the pyrolysis of carbon-containing fuels [8,9]. Other species, such as metals from material wear or heavy organic species such as tar, may contribute to what is measured as BC [10].

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