Abstract
We consider the multidirectional swelling and drying of hydrogels formed from super-absorbent polymers and water, focusing on the elastic deformation caused by differential swelling. By modelling hydrogels as instantaneously incompressible, linear-elastic materials and considering situations in which there can be large isotropic strains (arising from swelling) while deviatoric strains remain small, it is possible to describe accurately a wider range of gel states than traditional linear elastic theories allow. An equation is derived relating the displacement field to the polymer fraction in such hydrogels, permitting the shape of the swelling gel to be determined as it evolves in time, using the formulation of Part 1 to find the local polymer fraction. We discuss the boundary conditions to be applied at the surfaces of a gel, both on the bulk elastic stress and on the pervadic (pore) pressure in the interstices. Similarities between the equation for the displacements and the equations of classical plate theory are investigated by considering a model problem of a slender cylinder with its base immersed in water drying by evaporation into the surrounding air. In this problem, there is differential drying along the axis of the cylinder, as the base remains swollen while the top dries. The results of our displacement formulation agree qualitatively with experiments that we have conducted, and provide a physical interpretation of the forced biharmonic equation describing the displacement field.
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