Abstract

Abstract Whole-rock trace element, field, and petrographical studies indicate that the protoliths of highly deformed metamorphic rocks of the Pie de Palo Complex, Argentina, formed in an oceanic setting like that of SW Pacific supra-subduction complexes (e.g., Lau Basin). Age constraints suggest that this Mesoproterozoic complex, which includes some of the most primitive Grenville-age magmas known on Earth, formed in < 60 million years. Amphibolites (Las Pirquitas/Quemado region) with N-MORB like light-depleted REE patterns and Hf/Ta/Th relations, associated with Fe-rich schists interpreted as hydrothermally altered lavas and gabbros, formed in a back-arc spreading centre. Other ultramafic/mafic units (Quebrada del Gato, Cerros Valdivia/Barboza) formed as arc cumulates, and (central region) as ridge or arc/back-arc lavas (including shoshonite). Intermediate and silicic schists/gneisses are interpreted as arc region greywackes and silicic lavas, and marbles as reef deposits. Quebrada del Gato gneisses with trace elements indicating high pressure residual mineral assemblages are interpreted as younger subduction-related magmas emplaced in a thickened crust. The Pie de Palo Complex probably formed offshore of eastern Laurentia, and subsequently collided with Laurentia east of the Llano uplift, Texas, in Grenvillian times. This block, along with the Precordillera, was rifted from Laurentia in the latest Precambrian, arriving in Gondwana by Ordovician time.

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