Abstract
The IR multiple photon dissociation of s-trioxane is reported. The molecule is dissociated with high efficiency at low fluences (i.e. 6 J cm −2) At high s-trioxane pressures, the dissociation is enhanced via V-V processes. Addition of He results in V-T deactivation of the energized molecule. The dissociation is well described by RRKM theory.
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