A kinetic study of multi-walled carbon nanotube synthesis by catalytic chemical vapor deposition using a Fe–Co/Al 2O 3 catalyst

Abstract

A kinetic study was performed to describe the initial specific rate of multi-walled carbon nanotube synthesis by catalytic chemical vapor deposition (CCVD) on a bimetallic cobalt–iron catalyst at high temperature using ethylene decomposition to solid carbon and gaseous hydrogen. The study uses a mass spectrometer that allows reaction rate to be inferred from the exhaust gas composition measurements. The aim is to obtain a better understanding of the elementary steps involved in the production of carbon nanotubes so as to derive phenomenological kinetic models in agreement with experimental data. The best models assume the elimination of the first hydrogen atom from adsorbed ethylene as rate determining step and involve a hydrogen adsorption weak enough to be neglected. It was proved that hydrogen partial pressure has no influence on initial reaction rate of carbon nanotube synthesis with the catalyst used for this study. Activation energy and ethylene adsorption enthalpy were found to be equal to around 130 and −130 kJ mol −1, respectively.