Abstract

The reaction of methyl radicals with methanol at 77 K has been studied. CH 3 radicals were produced by the photolysis of diphenylamine-CH 3I with UV light in a methanol glass. In the methanol samples the percentage of water or the isotopic composition of methanol were changed. The reaction of CH 3 radicals with methanol obeys the law C = C 0exp(− Kt 1 2 ) in all cases.

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