Abstract

Abstract Based on XRD and chemical analysis results, the hydrogen insertion compound of molybdenum oxide hydrate (H-hydrate) was suggested to be a genotypic compound of yellow molybdenum trioxide monohydrate, MoO3·H2O. H-hydrate was obtained in a hot HCl solution and in hot water from hydrogen molybdenum bronze, HxMoO3. The hydrogen bronze with x≤0.24 and the molybdenum species formed in the solution played a role in the formation of H-hydrate. In this process, a temporary dissolution of Mo5+ was observed at the beginning of the formation.

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