Abstract
AbstractCo‐crystallization of a cyanide‐bridged tetranuclear complex [Co2Fe2] with 4‐cyanophenol (CP) gave a hydrogen bonding donor–acceptor system, [Co2Fe2(bpy*)4(CN)6(tp*)2](PF6)2⋅2 CP⋅8 BN (1). 1 exhibited a three‐step phase transition between HT, IM1, IM2, and LT phases upon temperature variation. Variable temperature magnetic measurements and structural analyses revealed that the three‐step spin transition is caused by electron‐transfer‐coupled spin transitions (ETCSTs) accompanied with alteration of the hydrogen bonding interactions.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
