Abstract

The title compound, [Mg(C5H4NOS)2(H2O)2]·C10H8N2O2S2, is a two-component host–guest material. The 2,2′-di­thio­bis(pyridine N-oxide) molecule has crystallographic twofold symmetry. The metal complex lies on an inversion centre and associates via C—H⋯S interactions into chains which thread the 2,2′-di­thio­bis­(pyridine N-oxide) lattice in perpendicular directions. Hydro­gen bonds exist between the water mol­ecules of the di­aqua­magnesium units and the N—O groups of the host lattice.

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