Abstract
Irradiation of benzil in acetonitrile in the presence of (E)- and (Z)-but-2-enyl-, pent-2-enyl-, and hex-2-enyl-tributylstannanes afforded the corresponding (E)- and (Z)-homcallylic alcohols, respectively, with complete retention of the original double bond configuration in good yields.
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More From: Journal of the Chemical Society, Chemical Communications
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