A highly efficient NiCo2O4 decorated g-C3N4 nanocomposite for screen-printed carbon electrode based electrochemical sensing and adsorptive removal of fast green dye.

Abstract

Herein, we demonstrate the preparation and application of NiCo2O4 decorated over a g-C3N4-based novel nanocomposite (NiCo2O4@g-C3N4). The prepared material was well characterized through several physicochemical techniques, including FT-IR, XRD, SEM, and TEM. The electrochemical characterizations via electrochemical impedance spectroscopy show the low electron transfer resistance of NiCo2O4@g-C3N4 owing to the successful incorporation of NiCo2O4 nanoparticles on the sheets of g-C3N4. NiCo2O4@g-C3N4 nanocomposite was employed in the fabrication of a screen-printed carbon electrode-based innovative electrochemical sensing platform and the adsorptive removal of a food dye, i.e., fast green FCF dye (FGD). The electrochemical oxidation of FGD at the developed NiCo2O4@g-C3N4 nanocomposite modified screen-printed carbon electrode (NiCo2O4@g-C3N4/SPCE) was observed at an oxidation potential of 0.65V. A wide dual calibration range for electrochemical determination of FGD was successfully established at the prepared sensing platform, showing an excellent LOD of 0.13µM and sensitivity of 0.6912 µA.µM-1.cm-2 through differential pulse voltammetry. Further, adsorbent dose, pH, contact time, and temperature were optimized to study the adsorption phenomena. The adsorption thermodynamics, isotherm, and kinetics were also investigated for efficient removal of FGD at NiCo2O4@g-C3N4-based adsorbents. The adsorption phenomenon of FGD on NiCo2O4@g-C3N4 was best fitted (R2 = 0.99) with the Langmuir and Henry model, and the corresponding value of Langmuir adsorption efficiency (qm) was 3.72mg/g for the removal of FGD. The reaction kinetics for adsorption phenomenon were observed to be pseudo-second order. The sensitive analysis of FGD in a real sample was also studied.