A highly efficient and reusable amorphous Pd(ii)/crystal Pd(0)-grafted porous polymer framework for catalytic CO2 cycloaddition

Abstract

Herein, we have developed an elegant strategy to heterogenize a homogeneously active Pd-based catalyst via decoration on a porous polymer framework for the cycloaddition of CO2 and epoxides to cyclic carbonates under mild and solvent-free conditions.