A high value utilization process for coal gasification slag: Preparation of high modulus sodium silicate by mechano-chemical synergistic activation

Abstract

Coal gasification coarse slag (CGCS) is solid waste generated during coal gasification. The mainly treatment method of CGCS is storage and landfill, which causes severe environmental pollution and waste of land resources. Sodium silicate can be synthesized using CGCS after impurities are removed for the high content of amorphous silica. In this work, a novel method of acid activation depolymerization–dilute alkali dissociation is proposed to synthesize high-modulus, low-impurity sodium silicate using CGCS under mild conditions. In the acid activation depolymerization process, the content of impurities such as CaO and Fe2O3 can be reduced from over 30% to below 3%. SiO2 composition can be enriched from 35.75% to 60.60%. The SiOAl bond is broken, the coordination structures of Q4(2Al) and Q4(3Al) are depolymerized, and the reactive Q4(0Al) and Q3(0Al) coordination structures of amorphous silica are formed. Numerous defects appear in the aluminosilicate structure, exposing a large number of active SiOH bonds. Efficient desilicated ratio is increased from 7.59% to 73.45%. During the process of dilute alkali dissociation, a large number of reactive SiOSi bonds with network structure defects are broken with the destruction of hydroxyl groups, while SiO and SiOH bonds are formed. Amorphous silica is leached into the liquid phase in the form of oligomers, and high-modulus sodium silicate can be obtained. Under optimal conditions, the removal ratio of amorphous silica and modulus of sodium silicate can reach 80% and 3.53, respectively. The synthesized sodium silicate can be used to produce hydrated silica, adhesives and surface coatings. This process not only reduces pollution, but also alleviates the shortage of high-purity quartz sand resources and promotes the clean development of coal chemical enterprises.