A high-resolution, continuous δ13C record spanning the Ordovician–Silurian boundary on Anticosti Island, eastern Canada

Abstract

One of the best-exposed and most complete stratigraphic records from paleotropical areas spanning the Ordovician–Silurian (O–S) boundary is located on Anticosti Island, eastern Canada. Our study is the first one to sample strata superbly exposed at low tide along the west coast of Anticosti Island, thus providing a previously unexploited, nearly complete stratigraphic interval (∼300 m) at the O–S boundary for δ13C chemostratigraphy. A new high-resolution δ13C curve with more than 500 data points spaced at every ∼0.5 m has been produced, rectifying important pitfalls of previously published δ13C curves (i.e., low sampling resolution, variable sampling intervals, stratigraphic gaps). This new high-resolution δ13C curve displays a lower and an upper positive Hirnantian Isotope Carbon Excursion (HICE) recognized elsewhere around the globe. The ascending limb of the lower HICE starting from baseline values of +0.5‰ corresponds to the upper 20 m of the late Katian Vauréal Formation, but δ13C peak values of +2.5‰ occur in the lower part of the Hirnantian Ellis Bay Formation. In spite of a δ13C record segmented by a few stratigraphic hiatuses, the upper HICE, with its peak values of +4.5‰, is well recorded in the upper part of the Hirnantian Ellis Bay Formation. When compared with sections from around the globe, our δ13C curve displays a distinct long-term trend with a long sustained lower HICE followed abruptly by the upper HICE and return to baseline values of +0.5‰ prior to the Rhuddanian. The continued descending isotopic trend well into the Becscie Formation suggests that the O–S boundary may occur at a higher stratigraphic level (up to 30 m) than previously interpreted. Active subsidence combined with moderate initial water depths prior to the Hirnantian were key factors controlling the deposition of a thick O–S sedimentary succession with a few hiatuses on Anticosti Island and capturing a comprehensive, reliable δ13C record across this interval.