Abstract
Conventional thermoset coatings cannot be easily repaired and removed owing to their highly crosslinked structure. The investigation of repairable or removable coatings has been receiving extensive attention, but few reported coatings possess both features. In this work, a repairable and removable coating was developed through the curing of a modified Kraft lignin (L-COOH) with poly(ethylene glycol) diglycidyl ether (PEG-epoxy) in the presence of zinc catalyst. The L-COOH was prepared by functionalization of Kraft lignin with carboxylic acid groups. The cured material had a high lignin content (>47 wt %). At elevated temperatures (>140 °C), dynamic transesterification in the cured network was activated, which resulted in fast stress relaxation and imparted excellent repairability. If the vitrimer system was used as a coating for tin plates, it provided adequate hardness and adhesion properties. In addition, the lignin-PEG coating could be easily removed from the tin plate by using a mild (0.01-0.1 m) NaOH aqueous solution owing to the unique swelling ability of the coating in alkaline aqueous solution. With the assistance of ethylene glycol, this coating could achieve stress-free repairability in 15 min. This work demonstrates the first lignin-based repair- and removable epoxy coating based on vitrimer chemistry.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
